I went to school on Bill T about diaphragm making. I'm chagrined that it had me so apprehensive. Once you figure out a form, it's cake. Make a disk, stretch some panty hose material over the form, and paint on the flowable silicone with your finger. Two or maybe three coats and you've got a working diaphragm. Pretty easy. The silicone goes on nice and smooth.
I've made 3 diaphragms so far: 2 for diluters, and 1 for a Trieste. For the Trieste, I made a Bill T type top mold, and to get the proper flang-ey type interface, I used the Trieste bottom box for the form on that side.
That got me thinking about how to use a set of boxes as a mold for this kind of a diaphragm. All you really need is a support in the middle for the disk. I'd use pvc for that.
My next diaphragm project, hopefully using this technique, will be a Sportsways DH diaphragm for my DualAir. Fingers crossed!